ZPERIODIC/SPECTROMETER
Field guide · operating manual

How to read the instrument

A short manual. It covers every control, and — more to the point — what each one is for: how morphing the table and mapping properties turns the periodic table from a chart you memorize into patterns you can see. Every RUN button opens the live instrument already set up for that idea.

00 The 30-second operation

  1. Pick an arrangement. The same 118 tiles fly into a new shape — standard, long form, left-step, spiral, orbits, or the wave. The motion is the lesson: nothing is added or removed, only refolded.
  2. Map a property. Grouped into categories (family, state), periodic trends (electronegativity, ionization energy, effective charge) and physical properties (density, melting point, atomic mass). A plain-English readout under the table states the trend and why it happens.
  3. Hover an element. Its whole group — its column, the elements that share the same number of outer electrons and so behave alike — lights up gold; and its period — its row, one sweep of a shell filling up, running from an alkali metal to a noble gas — lights up blue. Everything else dims, so where the element sits is obvious at a glance.
  4. Click to lock it in. The readout panel loads mass, configuration, key properties, and a Bohr shell diagram drawn from its real electron shells. Click again to release.
  5. Locate or isolate. Type a name, symbol, or number to find an element; or click a family in the legend to light up just that family across any arrangement.
Open the instrument

01 The six arrangements

There has never been one "correct" periodic table. Chemists have folded the same sequence many ways, each exposing a different truth. Switch between them and watch what moves — the elements that travel farthest are the ones whose "home" is genuinely debated. The last one unrolls the table completely.

Arrangement 01 · the everyday table

Standard

The familiar 18-column shape. Its honest flaw: the lanthanides and actinides are torn out and parked below, purely so the chart fits on a page. Good for orientation; misleading about where those 28 elements really live.

Run
Arrangement 02 · the true width

Long form

The f-block slotted back between groups 2 and 3, where it chemically belongs. This is the real shape; we only chop it up to save paper. Watch the two detached rows slide up into place.

Run
Arrangement 03 · Charles Janet, 1928

Left-step — ordered by orbital filling

Re-sorted by the order electrons actually fill orbitals, which slides the s-block to the right. Its boldest claim: helium sits above beryllium, not above neon — because helium fills an s-orbital just like the alkaline-earth metals. A great argument-starter about what "belongs" with what.

See helium move
Arrangement 04 · continuity made visible

Spiral

One unbroken ribbon winding out from hydrogen. The standard table hides its seams; here you can trace atomic number with your finger and never lift it. Color it by family and the same families sweep past on every loop — that recurrence is periodicity.

Trace the thread
Arrangement 05 · periods as shells

Orbits

Each period drawn as a concentric ring, echoing the Bohr shell diagram in the readout panel. One full lap of a ring is exactly one period; the alkali metals all start at the top and the noble gases close each ring. A bridge between the flat chart and the atom underneath it.

Go around
Arrangement 06 · the periodic law, literally

Wave — the property becomes height

Unroll the whole table into a single row ordered by atomic number, and let the mapped property become height. The everyday 2-D table is really this wave, wrapped so its peaks stack into columns. Map ionization energy and watch the same spike return at every noble gas and the same trough at every alkali metal — the value doesn't drift, it repeats. That repeating function of atomic number is exactly what the word "periodic" means; here it stops being a definition and becomes a shape you can see.

See the wave

02 What shapes the table — shells & orbitals

The table's outline isn't a design choice. The blocks, the torn-out f-block, the left-step ordering — all of it is one thing drawn different ways: the order in which electrons stack into an atom. Here is the machinery underneath every arrangement above.

An electron doesn't circle the nucleus on a track. It occupies an orbital — a fuzzy region where it is likely to be. There are four types, and for the shape of the table only one fact about them matters: how many electrons each can hold.

s · holds 2
p · holds 6
d · holds 10
f · holds 14
the 18-column table = s (2) + d (10) + p (6) s 2 wide d 10 wide p 6 wide f · 14 wide the f-block is torn out below only to fit the page
Every block is exactly as wide as its orbital is roomy: s = 2, p = 6, d = 10, f = 14. The table isn't shaped this way by convention — it's shaped by how many electrons fit in each orbital.

That one fact is the key the whole app turns on. It is why the left-step arrangement — which orders elements by the orbital filling next — has the shape it does; why a shell (one Bohr ring, one period) fills left to right; and why the electron configuration in a readout reads as shell-number, orbital-letter, count. Click any element and the “P-BLOCK” tag or the 3p⁵ in its profile is this, made concrete.

03 The order the shells fill — aufbau

§02 showed what the orbitals are and how many electrons each holds. The other half of the story is the order they fill — and that order is the engine behind an element's electron configuration, behind the left-step arrangement (which literally sorts by it), and behind the block sequence itself. It runs by the aufbau principle — lowest energy first.

s p d f 1s1 2s2 2p3 3s4 3p5 3d7 4s6 4p8 4d10 4f13 5s9 5p11 5d14 5f17 6s12 6p15 6d18 7s16 7p19
Follow the arrows top to bottom: 1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p … — the small number in each box is its fill rank. This is the Madelung rule: each subshell fills in order of n + l. The famous quirk is the boxed pair: 4s (rank 6) fills before 3d (rank 7), even though 3d sits a row higher — a fourth-shell orbital slips in ahead of a third-shell one. This crossover is exactly why the left-step table sorts the way it does.
Where the rule bends — and it does

Chromium and copper break Madelung — and the usual excuse is itself too tidy

Madelung predicts the configuration of most elements, but not all — about twenty break it. The two everyone learns sit in the d-block: chromium is [Ar]3d⁵4s¹, not the predicted 3d⁴4s²; and copper is [Ar]3d¹⁰4s¹, not 3d⁹4s². The textbook explanation — that a half-filled and a completely-filled d-subshell are specially stable — is neater than the truth. It doesn't generalize: chromium's heavier twin tungsten is 5d⁴6s², ignoring the half-filled pattern entirely, and the row above tungsten is a mess of exceptions (niobium 4d⁴5s¹, ruthenium 4d⁷5s¹, palladium 4d¹⁰ with an empty 5s). The filled-shell pattern (copper, silver, gold) does hold up; the half-filled one barely does. Neither is magic — both come from how close the 4s and 3d energies sit, plus how electrons of parallel spin lower each other's energy. So the rule is an excellent predictor with real exceptions, and even the tidy story for the exceptions is a simplification worth distrusting. See it play out: open the Left-step table and press Play the orbital fill — chromium and copper flag themselves as it sweeps past.

Watch the orbitals fill

04 Isotopes — why the masses aren't whole numbers

Nearly every section here is about electrons. This one is about the nucleus, and it answers a question the property maps quietly raise: chlorine's mass reads 35.45 — so what is 0.45 of an atom? Nothing. The atomic mass on the table is an average.

Atoms of one element always have the same number of protons, but they can carry different numbers of neutrons. Those variants are isotopes. Chlorine comes as two: chlorine-35 and chlorine-37 (the number is the mass number — protons plus neutrons). A natural sample is a fixed 3-to-1 mix of the two, so the mass on the table is their weighted average — pulled toward 35 because 35 is three times as common.

≈75.8% ≈24.2% ³⁵Cl ³⁷Cl 35 36 37 mass number → 35.45
The white pointer is the weighted average — the number on the table. It lands at 35.45, sitting much closer to the tall ³⁵Cl bar than to ³⁷Cl, because chlorine-35 is three times as abundant. It is not a half-atom; no single chlorine atom weighs 35.45. It is what you get when you weigh a real, mixed sample.
The payoff — why the table isn't ordered by weight

Argon outweighs potassium, yet comes before it

18 Ar 39.95 19 K 39.10 fewer protons · heavier more protons · lighter

Argon has 18 protons and potassium 19, so potassium comes later on the table. Yet argon is the heavier of the two (39.95 vs 39.10) — because argon's dominant isotope, argon-40, carries more neutrons than potassium's potassium-39. Weight puts them in the wrong order; proton count puts them right. That single inversion is why the modern table is ordered by atomic number, not mass — the beat the history page is built on, and the anomaly the atomic-mass map flags in Experiment 04.

05 Reading the property maps

Color is where the table stops being a list and becomes a map. Each mode paints all 118 elements on one scale at once, so a trend that takes a paragraph to state becomes a gradient you can read in a second. Open any of them, then switch arrangements while the colors hold.

Trend · top-right

Electronegativity

Rises toward the top-right, peaking at fluorine; falls toward the bottom-left. It is how hard an atom tugs shared electrons — fiercest when the nucleus is small and barely shielded.

Map it
Trend · top-right

Ionization energy

Also climbs to the top-right and falls down each group. It is the energy to rip off an electron — hardest for the tightly-held noble gases, easiest for the big, loose alkali metals.

Map it
Mechanism · the cause

Effective charge (Zeff)

The pull a valence electron actually feels — the full nuclear charge minus the inner electrons screening it. Rises across a period, resets down a group. Estimated with Slater's rules from each element's configuration; click an element to see the shielding and net pull drawn out.

Map the cause
Extremes · the centre

Melting point

Peaks among the central transition metals — tungsten holds out to 3695 K — and collapses at the noble gases. Carbon is the nonmetal that refuses to melt.

Find the peak
Extremes · the d-block

Density

Concentrated in the middle of the d-block — osmium and iridium are the densest things on the chart — and featherweight among the gases up top.

Find the heavies
Trend · with atomic number

Atomic mass

Climbs almost monotonically with atomic number. Spot the rare inversions (argon > potassium) — the reason the modern table is ordered by proton count, not weight.

Show the climb
Snapshot · 0 °C

State of matter

Almost everything is solid. Only two elements are liquid (mercury, bromine); the handful of gases huddle at the top-right. A quick reality check on what the elements are actually like.

See the states
The trend and its reason, side by side

Ionization energy is what you measure — effective charge is why

Most students learn "ionization energy increases up and to the right" and stop there. Map ionization energy, then switch to effective charge without moving anything else: the two pictures land on almost the same shape. That's not a coincidence — it's the mechanism. The more net positive charge an outer electron feels (Zeff), the harder it is to pull away (ionization energy). Seeing the measured trend and its cause fall on the same gradient is the difference between memorizing chemistry and understanding it. Try it in the wave, too, where both trace the very same sawtooth.

Map ionization energy Now map the cause

06 Periodic trends — quick reference

Four trends explain most of chemistry's behaviour. Each comes down to a tug-of-war between how strongly the nucleus pulls and how far away (and how shielded) the outer electrons are. Two words do the heavy lifting below: a period is a row (read left to right across one), a group is a column (read top to bottom down one).

PropertyAcross a period →Down a group ↓Why
Atomic radiusdecreases →increases ↓ More protons pull the same shell in tighter across a row; each new row adds a whole shell further out.
Ionization energyincreases →decreases ↓ A closer, less-shielded electron is harder to remove. map it →
Electronegativityincreases →decreases ↓ Small, high-charge atoms grip bonding electrons hardest; fluorine wins. map it →
Metallic characterdecreases →increases ↓ Easily-lost outer electrons make metals; the metalloid staircase marks the hand-off to nonmetals.

07 Isoelectronic — Coulomb's law you can measure

The effective-charge map in §05 showed the nucleus's pull rising across a period as protons pile up. Here is that idea stripped to one variable: take seven species that all carry the same ten electrons, and just keep adding protons. Nothing else changes — so whatever happens to their size is the nuclear pull, and only the nuclear pull.

An ion is an atom that has lost or gained electrons. Line up N³⁻, O²⁻, F⁻, Ne, Na⁺, Mg²⁺ and Al³⁺ and one thing is pinned down: every one has exactly ten electrons — they are isoelectronic. What changes is the proton count, climbing from 7 to 13. More protons pulling on the same cloud draws it in tighter and tighter.

same 10 electrons — add protons, the cloud tightens nuclear charge +7 +13 → Ne neutral no ionic radius N³⁻ O²⁻ F⁻ Na⁺ Mg²⁺ Al³⁺ 146 pm140133 1027253.5 Z 789 111213
Every species holds the same ten electrons; only the nuclear charge changes. From N³⁻ to Al³⁺ the ionic radius falls from 146 pm to 53.5 pm — the ten-electron cloud collapses to barely a third of its width, reeled in by six extra protons. That is Coulomb's law made visible: hold the charge being pulled fixed, and size just tracks the pull. It is the same engine as the §05 effective-charge map, with the electron count nailed down so nothing else can move.
Where the tidy picture needs an asterisk

Neon has no place on this ruler — and which radii you use matters

Neon sits dead centre — ten electrons, neutral — yet it is drawn as a dashed marker, not a circle, on purpose. Neon forms no ionic compounds, so it has no ionic radius to measure. Its van der Waals size (~154 pm) comes from a completely different measurement and can't be compared to the ionic radii on either side; drawn to this scale it would falsely make neon the largest of the seven. The honest series is the six ions. One more caveat worth stating plainly: these are Shannon effective ionic radii (6-coordinate). A second common convention — crystal radii — runs about 14 pm larger for cations and smaller for anions (there, Na⁺ is 116 pm, not 102). The shrink is real in either set, but the two must never be mixed, or the trend gets distorted.

08 Two-minute experiments

The fastest way to learn from the instrument is to ask it a question and watch it answer. Each one opens already set up — give it a try, then poke around from there.

Experiment 01

Does helium really belong with the noble gases?

Open the left-step table with helium locked in. It now sits above beryllium, with the other noble gases far away. Switch back to Standard and watch it leap across to neon. Which home convinces you?

Run experiment
Experiment 02

Where on the table is an element most reactive?

Map ionization energy, then isolate the alkali metals. The deep-violet, easy-to-ionize corner is where metals give up electrons most readily — the most reactive metals live at the bottom-left.

Run experiment
Experiment 03

What are the toughest materials on the chart?

Map melting point and lock in tungsten. The glowing band through the centre of the d-block is exactly the family of refractory metals engineers reach for when nothing else survives the heat.

Run experiment
Experiment 04

Why is the table ordered by number, not weight?

Map atomic mass and find argon (18). Now look at its right-hand neighbour, potassium — it is lighter than argon, yet comes after it. These mass inversions are the clue that proton count, not weight, is the real organizing principle of the table.

Run experiment
Experiment 05

Which elements are liquid at room temperature?

Map state and hunt for the odd ones out. Of all 118 elements, only two are liquid near room temperature — bromine (35) and mercury (80). Everything else is solid or gas. See if you can spot both.

Run experiment
Experiment 06

Find the staircase between metals and nonmetals

Isolate the metalloids — boron, silicon, germanium, arsenic, antimony, tellurium (and, in this dataset, astatine). They form a diagonal staircase marking the fuzzy border where metals hand off to nonmetals. The semiconductors that run modern electronics live right on this line.

Run experiment
Experiment 07

Why won't the noble gases react?

Map ionization energy and isolate the noble gases. They sit at the very top of the scale — their electron shells are already full, so prising an electron loose costs more energy than almost anywhere else on the table. That stinginess is exactly why they are famously inert.

Run experiment
Experiment 08

Watch the word "periodic" come true

Switch to the spiral and map ionization energy. Follow the ribbon outward: a sharp peak flares at the end of every single loop — the noble gases. The property doesn't drift, it repeats. That regular recurrence is precisely what "periodic" means.

Run experiment
Experiment 09 · the table meets biology

Read the label on a bag of fertilizer

Every fertilizer bag carries three numbers — its N-P-K ratio — for nitrogen, phosphorus and potassium, the elements plants burn through fastest. This experiment lights up the full set a plant needs: those three macronutrients, three secondary ones (calcium, magnesium, sulfur), and eight micronutrients required in mere traces (boron, chlorine, manganese, iron, nickel, copper, zinc, molybdenum). Carbon, hydrogen and oxygen — most of the plant's actual mass — it pulls free from air and water, so they're not in the soil-fed set. The cool part: this shopping list for life is scattered clear across the table, drawing on alkali metals, nonmetals, transition metals and metalloids alike. The set stays lit as you switch arrangements — flip to the spiral to watch the nutrients sprinkle along the thread, and notice they all hug the centre. Since the spiral winds outward by atomic number, that means every essential nutrient is a light element: life is built from what's abundant and bioavailable. The one straggler reaching outward is molybdenum — the heaviest nutrient most plants need, and the metal at the heart of nitrogen fixation.

Light up the nutrients
Experiment 10 · the heaviest nutrient

The trace metal that unlocks nitrogen

Molybdenum is the heaviest element most plants need — and they need a vanishingly small amount of it, less than any other nutrient. Yet without it, nitrogen is almost useless to them. Molybdenum sits at the active site of two crucial enzymes: nitrogenase, which nitrogen-fixing bacteria use to pull inert N₂ straight out of the air, and nitrate reductase, which lets a plant turn soil nitrate into the raw material for protein. So the lone heavy outlier in the nutrient set is the very metal that makes the most important nutrient work. This experiment lights up nitrogen and molybdenum together and opens molybdenum's profile — note how far apart they sit on the table, yet how tightly their fates are linked.

Run experiment
Experiment 11 · the table meets the dentist

The liquid metal in a solid filling

A traditional dental filling is an amalgam — and its main ingredient is mercury, the one metal that's a liquid at room temperature (it doesn't freeze until −39 °C). Roughly half of the filling is liquid mercury, stirred into a powder of solids that melt far hotter: silver (962 °C), tin (232 °C) and copper (1085 °C). The famous "silver filling" is really all four. Map melting point and the split is stark: mercury sits alone at the cold end of the scale while its partners glow warm. Yet the paste sets within minutes into a solid hard enough to chew on for decades. That's the point worth sitting with — the mixture has none of its ingredients' extremes. It isn't a runny liquid like pure mercury, and it isn't a stubborn high-melting metal like silver or copper; combining elements makes a material the periodic table can describe the parts of but never predict the whole of. The table tells you what each element is; what they become together is a story it can only hint at.

Run experiment
Experiment 12 · reasoning from evidence

Strip an atom one electron at a time

Click sodium and find the successive ionization energies chart in its readout. The first electron comes off cheaply — then the second costs nine times as much. That wall is sodium hitting its noble-gas core: after the one loose outer electron is gone, the next has to be prised out of a full inner shell. You didn't assume sodium is +1; you can read it off the jump. This is the one place in the tool where measured numbers let you reason straight to a conclusion, not just recognise a color. Try magnesium (the wall comes after two) and aluminium (after three) — the position of the wall is the ion charge, every time. Nonmetals like oxygen show the same core wall, but they gain electrons in chemistry rather than strip all of theirs away, so the jump reveals the shell without predicting an ion. The chart covers elements 1–20, where every important jump lives; the values are measured, not modelled.

Strip sodium